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re: how to naturally process pet manure
21 mar 2000
elaine gallant  proclaims:
 
> composting does not have a bad odor. if you can smell anything, it requires
>more carbon-  yard clippings, hay, straw.

the practical handbook of compost engineering by roger t. haug, pe,
(lewis, 1993, 717pp, $99.95) has 153 pages on odor management,
including these

  theorems on odor management 

  theorem 1--most composting substrates smell

    no argument here, i hope. all of the substrates which enter a
    composting process must be viewed as potential sources of odorous
    molecules. this includes sludge, sawdust, yard wastes, wood chips,
    refuse, food wastes, and all the other substrates we may throw
    into the starting mix.

    somewhere in the history of composting we got the idea that, if
    left alone, mother nature would be odor free. i don't know how this
    idea arose, but i assure you that it is not true, particularly with
    most composting substrates. 

  theorem 2--mother nature never claimed to be odor free

    on many occasions i have heard speakers state with great pomp,
    "if composting is conducted properly there will be no odors."
    these speakers are never plant operators! such statements have been
    implicated as a leading cause of anxiety complex among operators.
    let me reassure the operators reading this book that i have never
    seen data to support such a claim. the starting substrates contain
    odorous compounds and more are formed as intermediates during the
    breakdown of complex substrates. yes, this includes aerobic
    metabolism. 

    boiling points and vapor pressures for some of mother natures's 
    favorite odor compounds were presented in table 16.1. ammonia and
    h2s boil at very low temperatures and will never stay in solution
    unless converted by ph to an ionized form... acetic acid, a favorite
    intermediate of aerobic microbes, has a vapor pressure of 100 mm hg
    at 63 c. no wonder vinegar smells even at room temperature!...
    
  theorem 3--thermophilic composting acts like a heat distillation process

    if you want proof for theorem 3, i offer the observation that hot
    sludge or garbage smells more than cold sludge or garbage... vapor
    phase concentration of a compound is proportional to its vapor
    pressure and the latter increases with temperature... therefore...

  theorem 4--some release of odorous compounds is inevitable
             during composting

  theorem 5--what smells ok to you is probably an odor to someone else

  theorem 6--mother nature doesn't much care what compost system you have

  theorem 7--it's not nice to fool mother nature with a bad design or
             bad operation

    some odors will be produced even with good design and
    proper operation...

  theorem 8--you really should know something about your substrates

    ...despite the best efforts of design engineers and the claims of
    equipment vendors you should always remember the following:

  theorem 9--odor treatment is never 100%

    the only possible exception to theorem 9 is thermal oxidation
    which is capable of near complete odor destruction...

    there has been a subtle but persistent tendency for the design
    community to ignore theorem 9. this leads to the following:

  theorem 10--many past designs didn't recognize theorem 9

    scrubbers and biofilters are often designed with no attention to
    dispersion of the treated gases. it is common to see scrubbers with
    short stub stacks, low outlet velocities, scrubbers located near
    large buildings with their plumes caught in the building downwash,
    rain caps on top of discharge stacks, and other examples of poor
    dispersion design. it's as though the designer assumed 100%
    deodorization. this should never be assumed... 

  theorem 11--the worst odor is never when you're there

  theorem 12--mother nature always disperses odor, but sometimes 
              she can use a little help

    ...even if you don't "enhance" the natural dispersion, the
    following is always true:

  theorem 13: know your micromet conditions

    all major facilities should consider building an on-site micromet
    station to warn of worst-case atmospheric conditions. this will
    allow the operators to take corrective actions and, hopefully,
    avoid an odor incident... it is important to always remember the
    following:

  theorem 14--there must be a receptor to have an odor

  theorem 15--most receptors are at ground level

    for point sources, such as exhaust stacks from scrubbers, dispersion
    can be enhanced by (1) increasing stack height, (2) increasing stack
    velocity to increase momentum rise, (3) providing reheat to increase
    thermal bouyancy, and (4) providing forced dilution with ambient air...

  theorem 16--you can stop all of the odor some of the time, but
	      you can't stop all of the odor all of the time

    ...engineers may want to hide theorem 16 from their politicians...

  theorem 17--don't despair, odors can be managed

    despite odor problems at some facilities, the future for composting
    is optimistic. the industry generally recognizes that odor compounds
    are likely to be released. recognition of the problem is the first
    step toward its solution...

nick




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